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Oh yes, The Family of Charles IV by Francisco Goya in 1800. The man in the shadows in background at left is Goya himself. Others, left to right (all dates are birth-death): Carlos Maria Isidro (1788-1855); the future Fernando VII (1784-1833); Maria Josefa (1744-1801), sister of Carlos IV; an unknown woman; María Isabel (1789-1848); Queen Maria Luisa (1751-1819); Francisco de Paula (1794-1848); King Carlos IV (1748-1819); Don Antonio Pascual, brother of the King (1755-1817); Carlota Joaquina (1775-1830, only part of head visible); Don Luis de Parma (1773-1803) and his wife Maria Luisa (1782-1824), holding baby Carlos Luis (1799-1883), the future Duke of Parma.
Which one, do you know?